Dear Mr. Fisher,
If the "protective sheath" to which you are referring is the ozone layer in our upper atmosphere, then there seems to be very little work done showing that any rocket propellants other than "solid-fuels" could cause a negative impact on the atmosphere's UV protection characteristics (see http://news.nationalgeographic.com/news/2009/04/090414-rockets-ozone.html). More work does need to be done to address fuel-environment impacts. But stopping altogether would be quite impossible, and sending humans to settle Mars, a few launches every few years (orbital alignments) would not significantly impact our environment when compared to telecommunication, weather and military satellite launches rates.
As to the cause of global-warming, I do not believe that there is a single source, nature provides ample variations, but human behavior and fossil fuel use has contributed significantly (and continues). I would suggest we all stop driving cars before we stop launching into space.
Bottom line, if we want to survive, we need to diversify off Earth.