Ian,
I was involved in a discussion at another website. My involvment was not as a main participant. I have copied edited parts of my few messages and include them below. I have removed all texts except for mine. The point I was making is that thermodynamic entropy is not yet explained. Skipping past it to expressions of statistical mechanics is not satisfying to me. I think the mathematical expression defining thermodynamic entropy is an example of the Limits of Mathematics. I began my posts with:
"Saying that thermodynamic entropy is energy in transit divided by temperature is not, I think, an answer to: What is thermodynamic entropy? What did Clausius discover? Whatever it is, it requires the passage of time. Clausius allowed for absorbtion of energy under conditions of equilibrium. Statistical expressions do not include this dependence upon time."
"The T in the definition of thermodynamic entropy represents thermal equilibrium conditions. There is no fluctuation in temperature included. Yet energy in transit is included in the Q. Energy is absorbed over time under conditions of thermal equilibrium. I am not arguing that this theoretical ideal condition is possible in the real world. I am saying that Clausius did discover something of fundamental importance and it is not yet explained to this day."
"Since the derivation includes only long established macroscopic type properties, though they relate to the internal state, shouldn't it be expected that thermodynamic entropy should be explainable as a similar macroscopic property."
I was then referred to this Link to Paper for a more logical and axiomatic explanation of thermodynamic entropy. I read the paper and responded:
"I see the paper as being analogous to reverse engineering. Equilibrium and entropy are assumed as givens. When the authors assume conditions of equilibrium, then they have already introduced temperature into their analysis. It is there from the beginning. It is represented by the presence of equilibrium. The scale used to quantify temperature is introduced later, but the scale is not the property of temperature. Equilibrium is the condition of constant temperature. Different conditions of equilibrium represent different temperatures. They represent conditions of relative hot and cold. The practice of avoiding using these words and the mathematical symbol of T for temperature is not sufficient for saying that they are absent in the analysis until derived later. Changes in levels of equilibrium, no matter how accomplished, introduce the flow of energy as a given. The analysis is formal and axiomatic, very logical. I prefer relying upon the original measureable properties. Entropy is not explained in a mechanical sense. It is not described as a measurable property analogous to heat, temperature, pressure or volume.
I still expect that it should be explanable as a macroscopic classical style property. I think that its mathematical expression does contain a contradiction. Heat is energy in transit while equilibrium appears to exclude energy in transit. I think that this contradiction, or apparent contradiction, is what needs to be resolved, and, thermodynamic entropy will then be revealed. Another way of looking at this is to say that: When we finally understand what temperature is, then we will quickly understand what thermodynamic entropy is."
I had stated earlier that: "Temperature is an indefinable property with indefinable units of measurement." My point is that temperature is not yet explained.
There was no interest shown or discussion regarding my last message. Anyway, I post it here not because it represents anyone else's view but my own, rather, I submit it for consideration, and possible correction by you and others, as a mathematical solution without a clear physical interpretation, and, a possible classic example of the limits of mathematics.
James